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Everyone wants their cars to use less fuel, right? I read the following passage about running the car fuel lean from this website:

Run the engine fuel-lean, that is, use excess air. It is well known that fuel-lean running improves the efficiency. In the old days, under cruising conditions, the engines always ran lean – about 15% excess air -- this was economical. So what happen to change this? The problem is the three-way (CO, UHC, NOx) catalyst used on engine exhausts. This only works if the engine air/fuel ratio (by mass) is stoichiometric (chemically correct). For gasoline this ratio is 14.6:1. The engine computer, acting in concert with the engine air flow sensor, electronic fuel injectors, and exhaust oxygen sensor, maintains the stoichiometric ratio for most of your driving. Only at this ratio can the catalyst both oxidize the CO and UHC (to CO2 and H2O) and chemically reduce the NOx (to N2). (UHC = unburned hydrocarbons.) What humankind needs is a lean-NOx catalyst. Then we could have increased efficiency and continue to be clean!

This passage seems to make total sense. Use more air and increase fuel efficiency. However, I don't understand why the catalytic converter can't handle or be adapted to handle more air in the engine.

What are the advantages and disadvantages to forcing air in to the engine by means of a turbo or supercharger that would justify a car doing or not doing it?

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Your quote tells why cars don't run lean, right? So the catalytic converter will function properly. Also, and air pump for an engine is called a "turbo" or a "supercharger". You may have heard of those. – JPhi1618 Jan 26 at 19:09
    
@JPhi1618 Oh yes that makes so much sense now. I'd better change the question a bit now that I've had that sudden realisation! – Max Goodridge Jan 26 at 19:11
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IIRC from other posts here, when running lean the combustion chamber temperature increases as you run lean. The higher temperature bring it's own issues. – cdunn Jan 26 at 19:21
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I like your intent, but it's still two questions, and "because catalytic converter" is still the answer to the first question. – JPhi1618 Jan 26 at 19:42
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"However, I don't understand why the catalytic converter can't handle or be adapted to handle more air in the engine." Because science - it's as simple as that. Remember that catalysts already use REALLY expensive metal because it's the only stuff that works, and the limits of what catalysts can handle are what set how the engine has to work. If you invent a lean-NOx catalyst that works at exhaust temperatures and costs less than $500 per car, every automotive manufacturer and environmental agency on Earth will sell their children for a chance to get that patent. But so far, no dice. – Graham Jan 27 at 12:13
up vote 19 down vote accepted

Lean ≠ More Air

I believe the source of the misunderstanding is in how the term "lean" is being interpreted.

A lean mixture doesn't indicate the presence of more air. It indicates the presence of a higher proportion of air compared to fuel (air-fuel ratio, or AFR).

Quick example

Mixture A has 1,000 g of air, 80 g of fuel. AFR = 1000/80 = 12.5

Mixture B has 100 g of air, 7 g of fuel. AFR = 100/7 = 14.3

Since 14.3 > 12.5, Mixture B is leaner than Mixture A, even though Mixture A has more air.

This is why @cdunn is right; the presence of a turbocharger or supercharger doesn't impact the ability of an appropriately-sized catalytic converter from doing its job.


So why is it not good for cats to run lean?

A catalytic converter is designed to scrub harmful gases out of exhaust gases. It does this through a chemical reaction that involves the presence of catalyst(s).

The most popular type of cat design today is the three-way catalytic converter, which handles three types of harmful gases:

  • nitrogen oxides (NOx, not NOS)
  • carbon monoxide (CO)
  • unburnt hydrocarbons (HC)

The catch is that cats work well in a narrow AFR window, as this image shows:

NOx, CO, HC vs AFR

  • Run too lean, and the cat will have a hard time scrubbing NOx out of the exhaust gases
  • Run too rich, and your tailpipe will have a lot more HC, CO content
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@Zaid- may want to edit nitrous oxides to nitrogen oxides because nitrous oxide is the same as NOS, or (N2O). Great answer, though! +1 from me. – Mustangguy809 Jan 26 at 23:09
    
@Mustangguy809 thanks! Updated as per your suggestion – Zaid Jan 27 at 8:07
    
Awesome answer. I'll push you into the ten zone :-) +1 – DucatiKiller Jan 27 at 8:38
    
So why is it not good for **cats** to run lean? wait, what? – Federico Jan 27 at 9:52
    
@Federico Looks like you missed the party ;) – Zaid Jan 27 at 10:52

It's not that the catalytic converter can't handle more air per se, it's that running lean increases the temperature of combustion (I actually don't know why, but now I'm curious) and the catalytic converter needs to run inside it's chemical operating range. Something to do with the chemistry that I also don't know.

As for advantages for turbo boost and supercharging, it's not just air that being increased, it's the air fuel mixture in correct proportion that's being increased. More air / fuel for every power stroke gives you more power. Disadvantage of turbochargers is that with the wrong design it will provide lots of power, but that power will lag the throttle.

The disadvantage of superchargers is that they are driven by the crankshaft through a belt which means they consume some power to do their job. They clearly produce more power than they consume, but it's still reduced by however much it consumes. Because turbochargers are driven by exhaust gases, their only side effect is a slight back pressure.

One other reason not to do this on your street car is that it will decrease your mileage (faster fuel consumption), and the additional power will put wear and tear on an engine that may or may not have been designed to handle it.

Hope that helps!

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In the first paragraph, do you mean the catalytic converter needs to run inside it's thermal operating range? – Max Goodridge Jan 26 at 20:11
    
Actually it's a chemical range as it turns out. The heat is a by product of having the right air / fuel ratio, but the correct ratio is what lets the catalytic work correctly. I believe @Zaid is posting something soon that explains it better than I am here. – cdunn Jan 26 at 20:16
    
So in a sense I was correct as it needs to be inside its ideal thermal range as well otherwise as you said the increased temperature will have a knock-on effect? – Max Goodridge Jan 26 at 20:27
    
Well, I'm not sure I'm following you. What I'm trying to say, and apparently not well, sorry about that, is that the air fuel ratio being off causes there to be a thermal side effect. But it's the chemical a/f ratio that must be right for the cat to work. – cdunn Jan 26 at 20:43
    
The leaner the mixture the more oxygen it has. More oxygen means more 'rapid oxidation' which means more heat. – DucatiKiller Jan 26 at 21:52

Lean operation vs exhaust catalysts:

The three-way catalytic converter fitted to gasoline vehicles can't operate under lean engine conditions because the reaction of NOx to nitrogen and oxygen is a reduction reaction, and for this to occur there needs to be a corresponding oxidation. In the three-way catalyst that is the oxidation of CO and hydrocarbons to CO2. If excess oxygen was present then the oxygen, rather than the NOx would act as the oxidising agent for CO and HCs - because it's a more powerful oxidising agent - and the NOx would remain unreacted.

Technology for reducing NOx without the presence of corresponding oxidisable gases in the engine exhaust does exist and is increasingly used on diesel engines, which do run lean. However it needs more equipment in the vehicle, adding cost and complexity, and some approaches require an additive which needs to be replenished as it's used up.

Lean burn technology has been used in gasoline engines in the past, but perhaps failed to catch on because of the tightening regulations on NOx emissions - it may make a reappearance as NOx reduction technology becomes more established.

Advantages and disadvantages of turbochargers and superchargers

Using a turbocharger or supercharger allows more power output for the same engine displacement - or, a smaller engine displacement for the same power output. This means the engine can be smaller and lighter, and smaller cylinders have lower friction losses. The latest small gasoline engines such as Ford's Ecoboost range typically use both supercharging and turbocharging to give high fuel efficiency.

The main disadvantage of turbocharging or supercharging is the added complexity and cost of the equipment, but this is increasingly seen as worthwhile for the efficiency gains.

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Nice answer! +1 for balanced simplicity :-) – DucatiKiller Jan 27 at 9:59

One additional point to touch on is that leaner and richer are relative to what conditions the engine already runs under. In terms of chemical reactions, car engines tend to run a little rich by default -- more fuel than is needed for all of the air -- because it reduces the frequency of detonations in the mixture.

If you alter things so they run leaner than the designed operation conditions, you may move into stoichiometric combustion. This means that all the fuel is consumed by all the air and the reactions are exactly balanced. This is also to detonations. This results in pinging (or knocking) and damage to the cylinders and pistons. If you change things to make it more lean by enough to move beyond the stoichiometric ratio, the threat of detonation is reduced but if you move too lean, you will increase the rate of misfires -- more damage to the engine (and the catalytic converter).

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Running a lean mixture by itself isn't necessarily going to cause detonation, pinging or knocking. WW2 era old timer piston aircraft pilots used to run seriously lean mixtures on long hauls to increase range and it was safe to do so when they were at cruising altitude and power settings. You'd never consider doing it in a climb or at a high power though.

With an automotive engine, you'd have to have adaptive programming that would adjust the mixture from rich to lean depending on what level of load the engine was under. On a long haul, level roadway at steady highway speeds, you could probably run lean a good amount of the time, but for your typical city style stop and go, or hilly terrain, you'd probably never be in a power range where it would be safe, efficient or effective.

As for emissions, running lean definitely does create Nitrogen Oxides, so that may be of added concern in smog prone areas.

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There is an additional reason for not running lean, which applies very well to turbocharged engines - the extra fuel creates a 'boundary layer' between the combustion products and the cylinder wall. This absorbs extra heat during combustion to help keep the chamber temperature within tolerance. Modded cars that run very high turbo/supercharger boost are frequently on the point of running too lean, in that the injectors cannot supply sufficient fuel to maintain this boundary layer, and the combustion chamber pressure/temperature increases. In extreme cases this results in detonation/knocking, and under high boost can cause physical piston damage.

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